Online ISSN: 1521-3773 Print ISSN: 1433-7851
Angewandte Chemie International Edition
Volume
41, Issue
15,
2002.
© 2002 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
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Online ISSN: 1521-3773 Print ISSN: 1433-7851 © 2002 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany |
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Cover Picture: Angew. Chem. Int. Ed. 15/2002 K. C. Nicolaou, Phil S. Baran Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2619::AID-ANIE2619>3.0.CO;2-0 |
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| Editorial | ||
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Editorial: Angewandte Weekly - Back to the Future! Peter Gölitz Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2621::AID-ANIE2621>3.0.CO;2-9 |
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| Graphical Abstract | ||
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Graphical Abstract: Angew. Chem. Int. Ed. 15/2002 Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2623::AID-ANIE2623>3.0.CO;2-Y |
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| Review | ||
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Approaches to the Description and Prediction of the Binding Affinity of Small-Molecule Ligands to Macromolecular Receptors Holger Gohlke, Gerhard Klebe Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2644::AID-ANIE2644>3.0.CO;2-O |
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The CP Molecule Labyrinth: A Paradigm of How Endeavors in Total Synthesis Lead to Discoveries and Inventions in Organic Synthesis K. C. Nicolaou, Phil S. Baran Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2678::AID-ANIE2678>3.0.CO;2-V |
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| Highlight | ||
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High-Performance Fibers from Spider Silk Stefan Kubik Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2721::AID-ANIE2721>3.0.CO;2-3 |
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The Decaphosphatitanocene Dianion - A New Chapter in the Chemistry of Naked Polyphosphorus Ligands Helmut Sitzmann Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2723::AID-ANIE2723>3.0.CO;2-S |
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| Communication | ||
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Polymorphic Forms of Rubidium Telluride Rb2Te Klaus Stöwe, Stephan Appel Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2725::AID-ANIE2725>3.0.CO;2-G |
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Irreversible Adsorption of Cellobiose, Ascorbic Acid, and Tyrosine to Hydrophobic Surfaces in Water and Their Separation by Molecular Stirring Guangtao Li, Karl Doblhofer, Jürgen-Hinrich Fuhrhop Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2730::AID-ANIE2730>3.0.CO;2-7 |
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Synthesis of Neo-Peptidoglycans: An Unexpected Activity of Proteases Nicole Wehofsky, Reik Löser, Andrij Buchynskyy, Peter Welzel, Frank Bordusa Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2735::AID-ANIE2735>3.0.CO;2-E |
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Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions Jens Griep-Raming, Sven Meyer, Torsten Bruhn, Jürgen O. Metzger Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2738::AID-ANIE2738>3.0.CO;2-X |
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2,3,5,6-Tetrafluorophenylnitren-4-yl: A Quartet-Ground-State Nitrene Radical Hans Henning Wenk, Wolfram Sander Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2742::AID-ANIE2742>3.0.CO;2-U |
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Conversion of Hexafluoropropene into 1,1,1-Trifluoropropane by Rhodium-Mediated CF Activation Thomas Braun, Daniel Noveski, Beate Neumann, Hans-Georg Stammler Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2745::AID-ANIE2745>3.0.CO;2-C |
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Barrier Height Titration by Tunable Photoionization Combined with Chemical Monitoring: Unimolecular Keto/Enol Tautomerization of the Acetamide Cation Radical Detlef Schröder, Jessica Loos, Roland Thissen, Odile Dutuit, Philippe Mourgues, Henri-Edouard Audier, Chava Lifshitz, Helmut Schwarz Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2748::AID-ANIE2748>3.0.CO;2-V |
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Titanium-Promoted Stereoselective Synthesis of Hydroindolones from p-Quinamines by Domino Conjugate Additions M. Carmen Carreńo, María Ribagorda, Gary H. Posner Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2753::AID-ANIE2753>3.0.CO;2-M |
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Enantioselective Total Synthesis of Angucyclinone-Type Antibiotics Rubiginones A2 and C2 M. Carmen Carreńo, María Ribagorda, Álvaro Somoza, Antonio Urbano Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2755::AID-ANIE2755>3.0.CO;2-A |
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Carbon-Carbon Double-Bond Formation from the Reaction of Organozinc Reagents with Aldehydes Catalyzed by a Nickel(II) Complex Jin-Xian Wang, Ying Fu, Yulai Hu Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2757::AID-ANIE2757>3.0.CO;2-Z |
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Mechanistic Features, Cooperativity, and Robustness in the Self-Assembly of Multicomponent Silver(I) Grid-Type Metalloarchitectures Annie Marquis, Jean-Pierre Kintzinger, Roland Graff, Paul N. W. Baxter, Jean-Marie Lehn Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2760::AID-ANIE2760>3.0.CO;2-1 |
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Electrochemical Modulation of Fluorophore Emission on a Nanostructured Gold Film Prashant V. Kamat, Said Barazzouk, Surat Hotchandani Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2764::AID-ANIE2764>3.0.CO;2-E |
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Valence-Ordering Structures and Magnetic Behavior of Metallic MMX Chain Compounds Minoru Mitsumi, Kouhei Kitamura, Ayumi Morinaga, Yoshiki Ozawa, Mototada Kobayashi, Koshiro Toriumi, Yasuhito Iso, Hiroshi Kitagawa, Tadaoki Mitani Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2767::AID-ANIE2767>3.0.CO;2-X |
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Highly Selective Transport of Organic Compounds by Using Supported Liquid Membranes Based on Ionic Liquids Luís C. Branco, Joăo G. Crespo, Carlos A. M. Afonso Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2771::AID-ANIE2771>3.0.CO;2-U |
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Lewis Acid Controlled Regioselective 1,2 and 1,4 Reaction of ,-Unsaturated Carbonyl Compounds with TiIV Enolates Derived from -Diazo -Keto Carbonyl Compounds Guisheng Deng, Xue Tian, Zhaohui Qu, Jianbo Wang Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2773::AID-ANIE2773>3.0.CO;2-I |
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First Evidence of Fast SHS Proton Transfer in a Transition Metal Complex Gabriel Aullón, Merc?Capdevila, William Clegg, Pilar González-Duarte, Agust?Lledós, Rubén Mas-Ballest?br> Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2776::AID-ANIE2776>3.0.CO;2-0 |
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[Ir4(CO)12]-Catalyzed Coupling Reaction of Imidazoles with Aldehydes in the Presence of a Hydrosilane to Give 2-Substituted Imidazoles Yoshiya Fukumoto, Katsutoshi Sawada, Motoyuki Hagihara, Naoto Chatani, Shinji Murai Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2779::AID-ANIE2779>3.0.CO;2-J |
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[Lewis Acid]+[Co(CO)4]- Complexes: A Versatile Class of Catalysts for Carbonylative Ring Expansion of Epoxides and Aziridines Viswanath Mahadevan, Yutan D. Y. L. Getzler, Geoffrey W. Coates Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2781::AID-ANIE2781>3.0.CO;2-S |
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Remarkably High 1,5-Diastereoselectivity in a Nickel-Catalyzed Conjugate Addition of Me2Zn and Carbonyl Compounds to 1,-Dienynes with Through-Space Coupling Akihiro Ezoe, Masanari Kimura, Takahiro Inoue, Masahiko Mori, Yoshinao Tamaru Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2784::AID-ANIE2784>3.0.CO;2-A |
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Total Synthesis of Polycephalin C and Determination of the Absolute Configurations at the 3,4 Ring Junction Deborah A. Longbottom, Angus J. Morrison, Darren J. Dixon, Steven V. Ley Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2786::AID-ANIE2786>3.0.CO;2-Z |
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A Dendritic Porphyrin Receptor for C60 Which Features a Profound Positive Allosteric Effect Masatsugu Ayabe, Atsushi Ikeda, Yohei Kubo, Masayuki Takeuchi, Seiji Shinkai Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2790::AID-ANIE2790>3.0.CO;2-W |
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Dinitrogen-Bond Cleavage in a Niobium Complex Supported by a Tridentate Aryloxide Ligand Hiroyuki Kawaguchi, Tsukasa Matsuo Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2792::AID-ANIE2792>3.0.CO;2-K |
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An Efficient Enantioselective Synthesis of (-)-Galanthamine Barry M. Trost, Weiping Tang Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2795::AID-ANIE2795>3.0.CO;2-2 |
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Monomeric Compounds Containing the cis-[V(O)(OH)]+ Core Evangelos J. Tolis, Manolis J. Manos, Anastasios J. Tasiopoulos, Catherine P. Raptopoulou, Aris Terzis, Michael P. Sigalas, Yiannis Deligiannakis, Themistoklis A. Kabanos Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2797::AID-ANIE2797>3.0.CO;2-R |
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Polyoxomolybdenum(V) Sulfite Complexes: Synthesis, Structural, and Physical Studies Manolis J. Manos, J. Derek Woollins, Alexandra M. Z. Slawin, Themistoklis A. Kabanos Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2801::AID-ANIE2801>3.0.CO;2-1 |
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Molecular Symmetry Breakers Generating Metal-Oxide-Based Nanoobject Fragments as Synthons for Complex Structures: [{Mo128Eu4O388H10(H2O)81}2]20-, a Giant-Cluster Dimer Leroy Cronin, Christian Beugholt, Erich Krickemeyer, Mark Schmidtmann, Hartmut Bögge, Paul Kögerler, T. Kim K. Luong, Achim Müller Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2805::AID-ANIE2805>3.0.CO;2-E |
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MoV/Pyrophosphate Polyoxometalate: An Inorganic Cryptate Charlotte du Peloux, Pierre Mialane, Anne Dolbecq, Jérôme Marrot, Francis Sécheresse Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2808::AID-ANIE2808>3.0.CO;2-X |
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A Patterned TiO2(Anatase)/TiO2(Rutile) Bilayer-Type Photocatalyst: Effect of the Anatase/Rutile Junction on the Photocatalytic Activity Tetsuro Kawahara, Yasuhiro Konishi, Hiroaki Tada, Noboru Tohge, Junji Nishii, Seishiro Ito Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2811::AID-ANIE2811>3.0.CO;2-# |
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A Breathing Ionic Crystal Displaying Selective Binding of Small Alcohols and Nitriles: K3[Cr3O(OOCH)6(H2O)3][-SiW12O40]16 H2O Sayaka Uchida, Masato Hashimoto, Noritaka Mizuno Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2814::AID-ANIE2814>3.0.CO;2-I |
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A Self-Assembled Porphyrin Box from meso-meso-Linked Bis{5-p-pyridyl-15-(3,5-di-octyloxyphenyl)porphyrinato zinc(II)} Akihiko Tsuda, Takeshi Nakamura, Shigeru Sakamoto, Kentaro Yamaguchi, Atsuhiro Osuka Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2817::AID-ANIE2817>3.0.CO;2-0 |
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Crystal Engineering of a Nanoscale Kagom?Lattice Brian Moulton, Jianjiang Lu, Ranko Hajndl, Srikanth Hariharan, Michael J. Zaworotko Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2821::AID-ANIE2821>3.0.CO;2-Y |
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Substrate Distortion by a -Mannanase: Snapshots of the Michaelis and Covalent-Intermediate Complexes Suggest a B2,5 Conformation for the Transition State Valérie M.-A. Ducros, David L. Zechel, Garib N. Murshudov, Harry J. Gilbert, Lóránd Szab? Dominik Stoll, Stephen G. Withers, Gideon J. Davies Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2824::AID-ANIE2824>3.0.CO;2-G |
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The Consequences of Chirality in Crowded Arenes - Macromolecular Helicity, Hierarchical Ordering, and Directed Assembly Mark L. Bushey, Austin Hwang, Peter W. Stephens, Colin Nuckolls Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2828::AID-ANIE2828>3.0.CO;2-T |
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C2-Symmetric Chiral Pentacyclic Guanidine: A Phase-Transfer Catalyst for the Asymmetric Alkylation of tert-Butyl Glycinate Schiff Base Tetsuya Kita, Angelina Georgieva, Yuichi Hashimoto, Tadashi Nakata, Kazuo Nagasawa Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2832::AID-ANIE2832>3.0.CO;2-Q |
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Stable Non-Push-Pull Phosphanylcarbenes: NMR Spectroscopic Characterization of a Methylcarbene Emmanuelle Despagnet, Heinz Gornitzka, Alexander B. Rozhenko, Wolfgang W. Schoeller, Didier Bourissou, Guy Bertrand Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2835::AID-ANIE2835>3.0.CO;2-8 |
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Stereoselective Pinacol-Type Rearrangement of 2,3-Epoxy Alcohols with Retention of Configuration Mediated by Bis(iodozincio)methane Seijiro Matsubara, Hiromasa Yamamoto, Koichiro Oshima Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2837::AID-ANIE2837>3.0.CO;2-X |
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The Selective Incorporation of Alkenes into Proteins in Escherichia coli Zhiwen Zhang, Lei Wang, Ansgar Brock, Peter G. Schultz Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2840::AID-ANIE2840>3.0.CO;2-# |
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Synthesis and Characterization of the Neutral Digallene ArGaGaAr and Its Reduction to Na2ArGaGaAr (Ar=2,6-Dipp2C6H3, Dipp=2,6-iPr2C6H3) Ned J. Hardman, Robert J. Wright, Andrew D. Phillips, Philip P. Power Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2842::AID-ANIE2842>3.0.CO;2-O |
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| Book Review | ||
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Book Review: Nomeclature of Organic Compounds. Principles and Practice. 2nd Edition. By Robert B. Fox and Warren H. Powell Karl-Heinz Hellwich Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2845::AID-ANIE2845>3.0.CO;2-6 |
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Book Review: Cross-Coupling Reactions - A Practical Guide. Edited by Norio Miyaura Lukas J. Goossen Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2845::AID-ANIE11112845>3.0.CO;2-Z |
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Book Review: Stereochemistry. By David G. Morris Heidi M. Muchall Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2846::AID-ANIE2846>3.0.CO;2-0 |
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Book Review: Nanoscale Materials in Chemistry. Edited by Kenneth J. Klabunde Alf Mews Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2847::AID-ANIE2847>3.0.CO;2-V |
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Book Review: Drug-Membrane Interactions. Analysis, Drug Distribution, Modelling, Methods and Principles in Medicinal Chemistry. By Joachim K. Seydel and Michael Wiese Jürgen-Hinrich Fuhrhop Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2849::AID-ANIE2849>3.0.CO;2-J |
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| Web Site | ||
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Web Site: A Free and Fast Chemical Reaction Search Ulrich Iserloh Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2851::AID-ANIE2851>3.0.CO;2-S |
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| Preview | ||
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Preview: Angew. Chem. Int. Ed. 15/2002 Published Online: 2 Aug 2002 DOI10.1002/1521-3773(20020802)41:15<2854::AID-ANIE2854>3.0.CO;2-A |